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(a) Which of the following octahedral complexes are chiral: cis- [CoCl2(en)2]^ , [Cr(ox)3]^3-, trans- [PtCl2(en)2]^2 ,[Ni(phen)3]^2 ,[RuBr4(phen)]^- cis-[RuCl(py)(phen) .2]^ ? (b) The solution ^31 P NMR spectrum of a mixture of isomers of the square planar complex [Pd(SCN)2(Ph2 PCH2 PPh2)] shows one broad signal at 298 K. At 228 K, two singlets and two doublets (J=82 Hz) are observed and the relative integrals of these signals are solventdependent. Draw the structures of the possible is
(a) Which of the following octahedral complexes are chiral: cis- [CoCl2(…
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